16:
We have established so far that our mishnah sets the earliest possible time for reciting the Shema 'at the end of the day' at "starrise". This, of course, is a variable; for the time when three stars will be visible in the night sky will depend (among other imponderables) on the state of the weather, the eyesight of the spectator and the magnitude of the stars. To further complicate matters, the sages are wont to distinguish between 'small' stars, 'medium' stars and 'large' stars. It is obvious that since they could have had no concept of magnitude, they must be referring to the luminosity of the stars. Clearly, the visibility of stars is intended to indicate varying degrees of the onset of darkness. 'Large' stars don't count, because they can be seen even before it is dark. The end of Shabbat (which requires an additional amount of non-sacred time to be added on to the sacred time of Shabbat [tosefet]) requires the visibility of three 'small' stars. For the purposes of reciting the Shema 'at the end of the day' the visibility of three 'medium' stars suffices.
17:
When we try to give these indications quasi-scientific determinae, we usually describe them in terms of the sun's declination below the horizon. Three medium stars are deemed to be visible when (at any given geographic location) the sun has declined 5.88° below the horizon; three small stars are deemed to be visible when the sun has declined 8.5° below the horizon. In 'real' terms the former occurs about 25 minutes after sunset and the latter about 40 minutes after sunset. (This explains why it is possible on motza'ei Shabbat [Saturday night] to recite the Evening Shema [= Evening Service] before the time for Havdalah.)
To be continued.